The first solid-phase synthesis of oligothiophenes

Authors
Malenfant, PRL Frechet, JMJ
Citation
Prl. Malenfant et Jmj. Frechet, The first solid-phase synthesis of oligothiophenes, CHEM COMMUN, (23), 1998, pp. 2657-2658
Citations number
31
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
23
Year of publication
1998
Pages
2657 - 2658
Database
ISI
SICI code
1359-7345(199812):23<2657:TFSSOO>2.0.ZU;2-T
Abstract
The solid-phase synthesis of asymmetric oligothiophenes on a chloromethylat ed macroporous resin, using an alternating sequence of bromination and Stil le coupling reactions, has been used to afford oligomers up to the pentamer in excellent yield and purity.