Xc. Gao et al., Electroluminescence from both a light-emitting layer and hole transport layer: spectral evidence for charge carrier tunneling injection, CHEM P LETT, 297(5-6), 1998, pp. 530-536
We investigate the electroluminescence spectra of a series of double- and t
riple-layered devices based on a rare-earth complex PTT,tris-(1-phenyl-3-me
thyl-4-isobutyryl-5-pyrozolone)-bis(triphenyl phosphine oxide) terbium. In
triple-layer devices, besides green electroluminescence from the light-emit
ting layer PTT, blue emission from the hole transport layer TPD (N,N'-bis (
3-methylphenyl)-N,N'-diphenyl-benzidine) occurs at high electric field stre
ngth (EFS) and its peak intensity increases with EFS, This indicates a char
ge carrier tunneling injection mechanism. At high EFS, the Fowler-Nordheim
(FN) plot is close to Linear, supporting the tunneling mechanism. The large
barriers at the cathode and anode interfaces are responsible for this FN b
ehavior. In double-layer devices where the 8-hydroxyquinoline-aluminum laye
r is absent, TPD emission dominates the electroluminescence, proving that P
TT possesses high electron mobility. (C) 1998 Elsevier Science B.V. All rig
hts reserved.