Ligand-to-ligand charge transfer in (2,2 '-biquinoline)bis(cyclopentadienyl)zirconium(IV) - Absorption and emission in the visible range

Authors
Kunkely, H Vogler, A
Citation
H. Kunkely et A. Vogler, Ligand-to-ligand charge transfer in (2,2 '-biquinoline)bis(cyclopentadienyl)zirconium(IV) - Absorption and emission in the visible range, EUR J INORG, (12), 1998, pp. 1863-1865
Citations number
36
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
12
Year of publication
1998
Pages
1863 - 1865
Database
ISI
SICI code
1434-1948(199812):12<1863:LCTI('>2.0.ZU;2-G
Abstract
The lowest energy electronic transition of [(cyclopentadienyl)-Zr-2(IV)(2,2 '-biquinoline)](2+), which appears in absorption at lambda(max) = 360 nm an d in emission at lambda(max) = 518 nm, is of the Cp---> big ligand-to-ligan d charge-transfer-type.