This paper concerns a number of commercially available coffee-like flavorin
g preparations, identifying certain dioxolane structures of particular inte
rest. The research was carried out by GC/MS, and spectral characterization
was performed of the compounds in question, and especially of the acetals a
nd ketals produced from compounds with carbonyl functions and 1,2-propylene
glycol, Some determinations by means of chiral gas chromatography and by I
sotope Ratio Mass Spectrometry (IRMS) have been useful in improving the ana
lytical characterization of certain dioxolanes.