Electrochemistry of hydrotalcite-supported bis(2-mercapto-2,2-diphenyl-ethanoate) dioxomolybdate complexes.

Authors
Domenech, A Ribera, A Cervilla, A Llopis, E
Citation
A. Domenech et al., Electrochemistry of hydrotalcite-supported bis(2-mercapto-2,2-diphenyl-ethanoate) dioxomolybdate complexes., J ELEC CHEM, 458(1-2), 1998, pp. 31-41
Citations number
54
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
ISSN journal
15726657 → ACNP
Volume
458
Issue
1-2
Year of publication
1998
Pages
31 - 41
Database
ISI
SICI code
Abstract
The redox properties of the hydrotalcite-intercalated bis(2-mercapto-2,2-di phenyl-ethanoate) dioxomolybdate(VI) complex are investigated by cyclic vol tammetry by using modified carbon paste electrodes and clay-modified electr odes. The electrochemical data provide evidence that boundary-associated sp ecies involving the VI, V and TV oxidation states of molybdenum are respons ible for the electroactivity. (C) 1998 Elsevier Science S.A. All rights res erved.