Derivatives of the molecular valence have been calculated ab initio within
the new non-finite-difference approach elaborated on earlier for the global
hardness and the Fukui function indices. The group of 10 five-membered-rin
g molecules C4H4X has been chosen for a test, using the exaltation of the t
otal magnetic susceptibility (Lambda) as a reference measure of their aroma
ticity. An excellent correlation has been found between the molecular valen
ce derivatives in the nucleophilic regime and the exaltation II, for both t
he aromatic and antiaromatic molecules. Calculation of the valence derivati
ves provides an absolute measure of aromatic character that is not directly
dependent on the size of the molecule and does not require adopting any st
andard reference molecule.