The spin-dependent momentum density of single-crystal ferromagnetic gadolin
ium was probed by the magnetic Compton profile technique. Comparison with e
lectronic structure calculations indicate that the local spin-density appro
ximation is adequate for describing the magnetic Compton profiles. Furtherm
ore, the linear combination of muffin-tin orbitals prescription compared fa
vourably with a full-potential method. We find that testing theory against
the experimental density of states is problematic. Our calculations also in
dicate that the spin density is sensitive to the treatment of the 5p electr
ons.