A gadolinium cryptate with two coordinated water molecules

Authors
Bligh, SWA Drew, MGB Martin, N Maubert, B Nelson, J
Citation
Swa. Bligh et al., A gadolinium cryptate with two coordinated water molecules, J CHEM S DA, (22), 1998, pp. 3711-3713
Citations number
29
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
22
Year of publication
1998
Pages
3711 - 3713
Database
ISI
SICI code
0300-9246(19981121):22<3711:AGCWTC>2.0.ZU;2-B
Abstract
An X-ray crystallographic structure determination of the nitrate salt of th e gadolinium imBT cryptate shows coordination of two water molecules; NMRD relaxometry of this cryptate reveals a relaxivity of 5.8 mM(-1) s(-1) (at 1 0 MHz, 298 K and pH 6), which is pH sensitive over the range 4-9.