A two-dimensional held-swept pulsed EPR method, anisotropy-resolved (AR)-EP
R, is introduced. AR-EPR is a powerful tool to disentangle the EPR spectra
of disordered systems into a second dimension. The technique is based on a
stimulated three-pulse echo sequence combined with sample spinning of varia
ble frequency around an axis perpendicular to the static magnetic field. In
paramagnetic systems with anisotropic interactions, AR-EPR can be applied
to improve the spectral resolution, to separate overlapped spectra, to dete
rmine small unresolved hyperfine splittings, and to evaluate principal valu
es and principal axes directions in cases where this information cannot be
obtained from standard held-swept EPR approaches. A detailed theoretical de
scription of AR-EPR is given and a number of model calculations are present
ed. The potential of the method is demonstrated by several experimental exa
mples.