Iridium-assisted, enantiospecific aliphatic C-H activation/iodination

Authors
Dorta, R Togni, A
Citation
R. Dorta et A. Togni, Iridium-assisted, enantiospecific aliphatic C-H activation/iodination, ORGANOMETAL, 17(25), 1998, pp. 5441-5444
Citations number
36
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
17
Issue
25
Year of publication
1998
Pages
5441 - 5444
Database
ISI
SICI code
0276-7333(199812)17:25<5441:IEACA>2.0.ZU;2-G
Abstract
The observation of an enantiospecific C-H bond activation, followed by iodi nation at an allylic position of a coordinated 1,5-COD ligand in a chiral I r-(I) complex upon addition of I-2 in CH2Cl2 is reported. The same reaction carried out in THF affords an allylic eta(3),eta(2)-COD derivative. Both r eaction products were characterized by X-ray diffraction.