We measured spin-polarized photoluminescence excitation spectra and spin-re
laxation times in rectangular GaAs/AlAs quantum wires (QWRs) with small (<2
0 nm) lateral sizes. We found that the degree of spin polarization had its
maximum value near the transition edge, and varied greatly with the excitat
ion photon energy. The results agreed qualitatively with theoretically anal
yzed spin-polarization spectra, where the heavy-hole-light-hole mixing stat
es in the one-dimensional (1D) valence subbands were taken into account. To
clarify the effects of 1D confinement on the spin-relaxation process, we a
lso investigated the temperature dependence of the spin-relaxation time in
the QWRs. A comparison of the QWR and quantum-well spin-relaxation times re
vealed that the spin-relaxation rate is reduced in 1D structures in the low
-temperature region of 15-80 K. [S0163-1829(98)01148-5].