From fruit-bodies of the Japanese mushroom Boletus laetissimus two polyene
pigments boleto-crocin A and B were isolated and their structures determine
d by spectroscopic methods. The compounds represent diamides of hexadecahep
taenedioic acid with isoleucine and either aspartic acid or asparagine. The
L-configuration of the amino acids was established after acid hydrolysis.
The structures of five structurally related minor pigments were elucidated
by LC-ESIMS. (C) 1998 Published by Elsevier Science Ltd. All rights reserve
d.