Persulfurated complexes of palladium(II) and platinum(II) with fluorinatedaryl-thiolates, X-ray structure of [Pt(SC6F5),(CH3SCH(CH3)CH(CH3)SCH3)]

Authors
Martin, E Toledo, B Torrens, H Lahoz, FJ Terreros, P
Citation
E. Martin et al., Persulfurated complexes of palladium(II) and platinum(II) with fluorinatedaryl-thiolates, X-ray structure of [Pt(SC6F5),(CH3SCH(CH3)CH(CH3)SCH3)], POLYHEDRON, 17(23-24), 1998, pp. 4091-4099
Citations number
24
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
17
Issue
23-24
Year of publication
1998
Pages
4091 - 4099
Database
ISI
SICI code
0277-5387(1998)17:23-24<4091:PCOPAP>2.0.ZU;2-N
Abstract
The syntheses of the persulfurated [M(SRF)(2)(CH3SCH(CH3)CH(CH3)SCH3)], M = Pd or Pt; R-F = C6F5 or C6F4H-4 compounds allow the separation of two dias tereomers and the NMR detection of five conformers (three anti and two syn) of each compound. H-1, F-19 and Pt-195 NMR data have been used to assign e ach conformer and to obtain their relative populations as well as to follow their equilibrium at high temperatures. The X-ray diffraction molecular an d crystalline structure of [Pt(SC6F5)(2)(CH3SCH(CH3)CH(CH3)SCH3)] has been determined. (C) 1998 Elsevier Science Ltd. All rights reserved.