Sy. Jiao et al., Investigation and modelling of the thermal cracking of waste plastics derived oil in a downer reactor, PROCESS SAF, 76(B4), 1998, pp. 319-331
Given the current abundance of waste plastics and the new technology to con
vert them into highly marketable products, waste plastics are projected as
an alternative feedstock for producing some key organic products such as pr
ofitable alpha-olefins and paraffins through thermal cracking. This work wa
s carried out to investigate the kinetics and to model the thermal cracking
of waste plastics derived oil in a downer reactor by means of computer sim
ulation. Attention was focused on the formation of the model for the waste
plastic oil conversion, taking into account the process reaction kinetics,
fluid mechanics, and heat transfer in the gas-solid downflow system, and th
e subsequent investigation of the model predictions under various condition
s. Simulation results show that the downer reactor can achieve a high yield
of the desired Medium Ends (ME) containing significant amount of alpha-ole
fins under a short residence time for a given conversion of liquefied waste
plastics.