The sila-pummerer rearrangement of 3,3-dimethyl-3-silathiane S-oxide

Authors
Kirpichenko, SV Suslova, EN Albanov, AI Shainyan, BA
Citation
Sv. Kirpichenko et al., The sila-pummerer rearrangement of 3,3-dimethyl-3-silathiane S-oxide, TETRAHEDR L, 40(1), 1999, pp. 185-188
Citations number
24
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
1
Year of publication
1999
Pages
185 - 188
Database
ISI
SICI code
0040-4039(19990101)40:1<185:TSRO3S>2.0.ZU;2-Q
Abstract
The thermal conversion of sulfoxide 1 into the O-silylated cyclic O,S-aceta l (2) is the first example of the sila-Pummerer rearrangement of cyclic org anosilicon sulfoxides leading to ring expansion. The kinetics of the rearra ngement are studied and thermodynamic parameters are determined. The result s are in compliance with mechanism involving a pentacoordinated silicon ato m. (C) 1998 Elsevier Science Ltd. All rights reserved.