Citation
J. Terao et al., Titanocene-catalyzed double silylation of dienes and aryl alkenes with chlorosilanes, TETRAHEDR L, 39(52), 1998, pp. 9697-9698
Citations number
6
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039
→ ACNP
Volume
39
Issue
52
Year of publication
1998
Pages
9697 - 9698
Database
ISI
SICI code
0040-4039(199812)39:52<9697:TDSODA>2.0.ZU;2-O
Abstract
Double silylation of 1,3-butadienes with chlorosilanes was found to proceed
by using titanocene dichloride as the catalyst in the presence of "BuMgCl,
giving rise to 1,4-disilylated 2-butenes in good yields. Aryl substituted
alkenes also afforded 1,2-disilylated products under similar conditions. (C
) 1998 Elsevier Science Ltd. All rights reserved.