Efficient syntheses of penta-hydroxylated cyclohexanones via PdCl2-mediated Ferrier-II reaction of 6-O-acetyl-5-enopyranosides

Authors
Takahashi, H Kittaka, H Ikegami, S
Citation
H. Takahashi et al., Efficient syntheses of penta-hydroxylated cyclohexanones via PdCl2-mediated Ferrier-II reaction of 6-O-acetyl-5-enopyranosides, TETRAHEDR L, 39(52), 1998, pp. 9703-9706
Citations number
17
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
39
Issue
52
Year of publication
1998
Pages
9703 - 9706
Database
ISI
SICI code
0040-4039(199812)39:52<9703:ESOPCV>2.0.ZU;2-0
Abstract
The conversion of 6-O-acetyl-5-enopyranosides into fully oxygenated cyclohe xanones was found to proceed efficiently with a catalytic amount of palladi um chloride under neutral conditions. This method was proved to be superior in efficacy to the conventional Hg method. (C) 1998 Elsevier Science Ltd. All rights reserved.