KINETIC RESOLUTION OF EUCARVONE TRICARBONYLIRON COMPLEX WITH SPARTEINE-N-OXIDES

Authors
PETROWITSCH T EILBRACHT P
Citation
T. Petrowitsch et P. Eilbracht, KINETIC RESOLUTION OF EUCARVONE TRICARBONYLIRON COMPLEX WITH SPARTEINE-N-OXIDES, Synlett, (3), 1997, pp. 287
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
3
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):3<287:KROETC>2.0.ZU;2-0
Abstract
The kinetic resolution of the racemic eucarvone complex 1 using chiral amine oxides 3a-c as oxidizing agents leads to optically enriched com plexes 1 and 2 with up to 64 % ee. The absolute configuration of the c hiral complexes 1 and 2 is determined by their CD spectra.