Optical remote sensing of ocean color is a well-established technique for i
nferring ocean properties. However, most retrieval algorithms are based on
the assumption that the radiance received by satellite instruments is affec
ted only by the phytoplankton pigment concentration and correlated substanc
es. This assumption works well for open ocean water but becomes questionabl
e for coastal waters. To reduce uncertainties associated with this assumpti
on, we developed a new algorithm for the retrieval of marine constituents i
n a coastal environment. We assumed that ocean color can be adequately desc
ribed by a three-component model made up of chlorophyll a, suspended matter
, and yellow substance. The simultaneous retrieval of these three marine co
nstituents and of the atmospheric aerosol content was accomplished through
an inverse-modeling scheme in which the difference between simulated radian
ces exiting the atmosphere and radiances measured with a satellite sensor w
as minimized. Simulated radiances were generated with a comprehensive radia
tive transfer model that is applicable to the coupled atmosphere-ocean syst
em. The method of simulated annealing was used to minimize the difference b
etween measured and simulated radiances. To evaluate the retrieval algorith
m, we used simulated (instead of measured) satellite-received radiances tha
t were generated for specified concentrations of aerosols and marine consti
tuents, and we tested the ability of the algorithm to retrieve assumed conc
entrations. Our results require experimental validation but show that the r
etrieval of marine constituents in coastal waters is possible. (C) 1998 Opt
ical Society of America.