Effect of Ag doping on structure and critical temperature of Bi2Sr2CaCu2O8+delta superconductors

The effects of Ag substitution for Bi, Sr and Cu on the c-axis lattice para meter and critical temperature (T-c) were determined for the Bi2-xSr2-yCaCu 2-zO8+delta(BSCCO-2212) superconducting phase. Two distinct regimes of beha vior were observed: fast cooling represented the regime where the uptake of excess oxygen was the controlling factor and slow cooling represented the regime where the cation content was the controlling factor on the structure and properties, Samples showed higher T-c values and longer c-axes with in creased cooling rate. A linear increase in T-c with increase in c-axis leng th was observed for the faster-cooled samples. For the slow-cooled samples, increased c-axis length was observed when Ag was substituted for Bi and Sr , whereas substituting Ag for Cu caused no change in c-axis length. In addi tion, any deviation from the ideal 2212 stoichiometry was shown to reduce t he T-c values of samples that were slowly cooled and fully oxygenated. Prel iminary results obtained by high-resolution transmission electron microscop y coupled with electron energy loss spectroscopy indicated that relatively small amounts of Ag (approximate to 1 at.%) can occupy Bi sites and a large r amount(approximate to 10 at.%) of Ae can substitute for Cu. (C) 1998 Publ ished by Elsevier Science Ltd. All rights reserved.