Hydrothermal assembly and structural characterisation of one- and two-dimensional organic/inorganic hybrid materials constructed from diphosphopentamolybdate(VI) clusters and {Cu(en)}(2+) complex groups

Three novel low-dimensional organic/inorganic hybrid materials, assembled h ydrothermally, are constructed from diphosphopentamolybdate(VI) clusters li nked through {Cu(en)}(2+) groups; the initial Mo/Cu and Mo/en ratios and th e use of F- ions control the connectivity between the phosphomolybdate clus ters and {Cu(en)}(2+) groups, and hence the dimensionality of the solid arc hitectures.