Enantioselective palladium catalyzed allylic substitution with chiral thioether derivatives of ferrocenyl-oxazoline and the role of planar chirality in this reaction

Authors
You, SL Zhou, YG Hou, XL Dai, LX
Citation
Sl. You et al., Enantioselective palladium catalyzed allylic substitution with chiral thioether derivatives of ferrocenyl-oxazoline and the role of planar chirality in this reaction, CHEM COMMUN, (24), 1998, pp. 2765-2766
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
24
Year of publication
1998
Pages
2765 - 2766
Database
ISI
SICI code
1359-7345(199812):24<2765:EPCASW>2.0.ZU;2-E
Abstract
A series of chiral thioether dervatives of ferrocenyl-oxazolines, prepared with diastereoselectivities > 95:5, have been shown to be highly efficient catalysts for a palladium catalyzed allylic substitution reaction, with ena ntioselectivity of 81-98% ee, and the role of planar chirality in these lig ands was also discussed.