Raman and luminescence spectroscopy have been used for the first time to de
termine the interface fracture energy for single-fibre composites. By using
the measured fibre stress distributions in single-fibre fragmentation comp
osite specimens and a simple energy-balance scheme, the energy for the init
iation of interfacial debonding has been estimated for carbon (T50) and alp
ha-alumina (PRD-166 and Nextel 610) fibres embedded in epoxy resins. It has
been found that the interface fracture energy shows good sensitivity to ch
anges in the level of fibre/matrix adhesion clue to surface treatment and s
izing of the fibres. It is also found that the values of interface fracture
energy correlate well with measured values of interfacial shear strength d
etermined for the same fibre/matrix systems. (C) 1998 Elsevier Science Ltd.
All rights reserved.