It has been found experimentally that phase diagram for the system Bi2O3-Ca
O-SrO-CuO in SrO-rich region at 850 degrees C in the open air includes thre
e elementary tetrahedra: CaO-SrO-Sr6Bi2O11-Sr2CuO3, CaO-Sr2CuO3-Sr6Bi2O11-S
r3.5Ca0.5Bi2O7 and Sr3Bi2O6-Sr6Bi2O11-Sr3,5Ca0,5Bi2O7- Sr2CuO3 In the consi
dered interval of corresponding oxide concentrations quaternary oxides are
not formed under the above conditions.