A new silyl substituted arachno-tetraborane(8) derivative

Authors
Wesemann, L Ramjoie, Y Wagner, T
Citation
L. Wesemann et al., A new silyl substituted arachno-tetraborane(8) derivative, INORG CH C, 1(11), 1998, pp. 443-445
Citations number
29
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
1
Issue
11
Year of publication
1998
Pages
443 - 445
Database
ISI
SICI code
1387-7003(199811)1:11<443:ANSSAD>2.0.ZU;2-2
Abstract
The reaction of nido-B5H9 with MeHSi(NMe2)(2) yields a new silyl substitute d tetraborane(8) derivative (Me2N)(2)BH2MeSiB4H8 (1). The silyl substituent is part of a new four membered ring system SiR2(NR2')(2)BH2+. The reaction product has been characterized by X-ray crystallography, multinuclear and multidimensional NMR spectroscopy, mass spectrometry and elemental analyses . (C) 1998 Elsevier Science S.A. All rights reserved.