The development of new working pairs and cycles extends the field of applic
ation of absorption systems with corresponding environmental benefits. The
performance of standard cycles can be enhanced, e.g. by multi-staging. For
each application the suitable working pair and cycle can be chosen regardin
g thermodynamical and economical aspects. Still, the performance strongly d
epends on the given external conditions. In this paper, basic thermodynamic
constraints stemming from those conditions and valid for all sorption cycl
es are derived using the concept of endo-reversibility. Fundamental economi
c conclusions can be drawn. Subsequently, real machines are analysed. A com
parison with manufacturers data and experimental data is made. The working
pairs lithium bromide/water and binary hydroxide solution/water are discuss
ed. (C) 1998 Elsevier Science Ltd and IIR. All rights reserved.