Synthesis and characterization of fluoro azido-carbondisulfide, F-SCSN3, and a new synthesis for azido-carbondisulfide, N3SCS-SCSN3

Authors
Crawford, MJ Klapotke, TM
Citation
Mj. Crawford et Tm. Klapotke, Synthesis and characterization of fluoro azido-carbondisulfide, F-SCSN3, and a new synthesis for azido-carbondisulfide, N3SCS-SCSN3, J FLUORINE, 92(2), 1998, pp. 153-156
Citations number
32
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
92
Issue
2
Year of publication
1998
Pages
153 - 156
Database
ISI
SICI code
0022-1139(19981102)92:2<153:SACOFA>2.0.ZU;2-N
Abstract
A new and improved synthesis for azido-carbondisulfide, N3SCS-SCSN3 (1), is reported from sodium azido-dithiocarbonate, [Na][SCSN3], and xenon difluor ide in aqueous solution. Treatment of azido-carbondisulfide, N3SCS-SCSN3 (1 ), with elemental fluorine in SO2ClF solution at -100 degrees C yielded the new compound fluoro azido-carbondisulfide, F-SCSN3 (2), as a pale yellow s olid. F-SCSN3 (2) was characterized by infrared and Raman spectroscopy and quantum chemical DFT computations. The structures of both compounds, N3SCS- SCSN3 (1) and F-SCSN3 (2), have been elucidated by a combined theoretical ( DFT) and experimental (IR, Raman) study. (C) 1998 Elsevier Science S.A. All rights reserved.