Matrix line in pulsed electron-nuclear double resonance spectra

Authors
Astashkin, AV Kawamori, A
Citation
Av. Astashkin et A. Kawamori, Matrix line in pulsed electron-nuclear double resonance spectra, J MAGN RES, 135(2), 1998, pp. 406-417
Citations number
24
Categorie Soggetti
Chemistry & Analysis","Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MAGNETIC RESONANCE
ISSN journal
10907807 → ACNP
Volume
135
Issue
2
Year of publication
1998
Pages
406 - 417
Database
ISI
SICI code
1090-7807(199812)135:2<406:MLIPED>2.0.ZU;2-8
Abstract
The intense line in Mims and Davies electron-nuclear double resonance (ENDO R) spectra due to the hyperfine interactions of an unpaired electron with d istant matrix nuclei is shown to originate from a simultaneous inversion of a large number of nuclear spins by a radiofrequency pulse. Theoretical exp ressions describing the matrix ENDOR effect are derived and verified experi mentally. (C) 1998 Academic Press.