The (1 0(0) 5)(1,2) --> (1 0(0) 4)(1,2) and (1 0(0) 6)(1,2) --> (1 0(0) 5)(
1,2) emission bands of (CO2)-C-12-O-16 have been recorded near 4.5 mu m by
Fourier transform spectroscopy of a CO2 + N-2 mixture excited by de dischar
ge. The spectroscopic parameters of the (1 0(0) v(3))(1,2) vibrational stat
es with v(3) = 0-6 have been obtained from a global rotational analysis of
the six (1 0(0) v(3))(1,2) --> (1 0(0) (v(3)-1))(1,2) emission bands (v(3)
= 1-6). The (1 0(0) 5)(1,2) vibrational states of both (CO2)-C-12-O-16 and
(CO2)-C-13-O-16 have been observed by direct absorption from the vibrationa
l ground state by Intracavity Laser Absorption Spectroscopy near 12 700 and
12 400 cm(-1), respectively. The rovibrational energy levels obtained by t
he two experimental techniques are discussed and compared with those calcul
ated in the framework of the effective operator approach. (C) 1999 Academic
Press.