Radiation qualities of mercury high-frequency electrodeless light sources (
HFELSs) of natural and 202 isotope abundance of 99.8% have been studied in
order to optimize filling and operation of the source. The optimal mercury
vapour pressure in a high-frequency electrodeless inductive coupled dischar
ge is estimated. A qualitative explanation of the excitation and ionization
processes is given. An application of nonlinear multiparameter chi-square
line shape fitting in order to find the true profile of spectral lines and
equipment influence is presented. We demonstrate that, by appropriate selec
tion of both the HF-oscillator working mode and Hg vapour pressure, it is p
ossible to change the intensity and profile of the spectral lines quickly,
making the use of the mercury HFELSs in various applications possible.