Critical initial conditions for spontaneous thermal ignition

Citation
Ro. Weber et al., Critical initial conditions for spontaneous thermal ignition, J CHEM S F, 94(24), 1998, pp. 3613-3617
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS
ISSN journal
09565000 → ACNP
Volume
94
Issue
24
Year of publication
1998
Pages
3613 - 3617
Database
ISI
SICI code
0956-5000(199812)94:24<3613:CICFST>2.0.ZU;2-X
Abstract
Critical initial conditions for thermal ignition are calculated numerically for planar, cylindrical and spherical geometries. In each case a compariso n is made on the bifurcation diagram with the intermediate steady state(s). It is clearly seen that the actual critical initial condition which depend s upon the initial temperature profile, is partly below the intermediate st eady state(s). The variation with ambient temperature, exothermicity and Bl ot number are all explicitly shown. The results are important for calculati ons relevant to the critical hot product assembly problem where a hot manuf actured organic product is packed into containers or stockpiled at a subcri tical ambient storage temperature. An example calculation for an interestin g case study (milk powder) is given to illustrate the utility of our result s.