Synthesis of vinyl epoxides via a three-component coupling

Authors
Rowbottom, M Mathews, N Gallagher, T
Citation
M. Rowbottom et al., Synthesis of vinyl epoxides via a three-component coupling, J CHEM S P1, (23), 1998, pp. 3927-3929
Citations number
30
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
0300922X → ACNP
Issue
23
Year of publication
1998
Pages
3927 - 3929
Database
ISI
SICI code
0300-922X(199812):23<3927:SOVEVA>2.0.ZU;2-C
Abstract
The butadienylsulfonium species 1 undergoes stepwise addition of a stabilis ed enolate followed by trapping of the initially formed S-ylid 2 with an al dehyde to provide vinyl epoxides 3 in a two-step, three-component process.