Polymerization and copolymerization of metal-containing monomers as the method of synthesizing structurally organized catalysts

Citation
Gi. Dzhardimalieva et Ad. Pomogailo, Polymerization and copolymerization of metal-containing monomers as the method of synthesizing structurally organized catalysts, KINET CATAL, 39(6), 1998, pp. 821-826
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
KINETICS AND CATALYSIS
ISSN journal
00231584 → ACNP
Volume
39
Issue
6
Year of publication
1998
Pages
821 - 826
Database
ISI
SICI code
0023-1584(199811/12)39:6<821:PACOMM>2.0.ZU;2-W
Abstract
The method of the synthesis of polymeric metal-complex catalysts by the pol ymerization and copolymerization of metal-containing monomers is discussed. The polymerization of the metal-containing monomers based on acrylates, ma leates, fumarates, itaconates, and acetylnecarboxylates of transition metal s are studied. The relative reactivity constants of monomers and the distri bution of the metal-containing monomer links in the copolymer chain are det ermined. The catalytic properties of the metal-polymer complexes obtained i n the course of hydrogen peroxide decomposition are studied.