Gi. Dzhardimalieva et Ad. Pomogailo, Polymerization and copolymerization of metal-containing monomers as the method of synthesizing structurally organized catalysts, KINET CATAL, 39(6), 1998, pp. 821-826
The method of the synthesis of polymeric metal-complex catalysts by the pol
ymerization and copolymerization of metal-containing monomers is discussed.
The polymerization of the metal-containing monomers based on acrylates, ma
leates, fumarates, itaconates, and acetylnecarboxylates of transition metal
s are studied. The relative reactivity constants of monomers and the distri
bution of the metal-containing monomer links in the copolymer chain are det
ermined. The catalytic properties of the metal-polymer complexes obtained i
n the course of hydrogen peroxide decomposition are studied.