The first mesoporous materials (pore diameter between 20 and 100 Angst
rom) were discovered just five years ago. A new approach to mesoporous
materials by direct templating of lyotropic liquid crystals is review
ed and compared with strategies reported previously, The direct templa
ting method is shown to be very versatile. It is suggested that the re
sulting materials can almost be termed ''second generation'' mesoporou
s materials, owing to the broad variety of mesoporous structure and si
ze, high degree of ordering, and low incidence of defects.