A new method of electronprobe microanalysis (EPMA) is suggested. It is
based on creating ionic conductivity in frozen water solutions and in
polymer films by doping them with a salt. This procedure is effective
to prevent surface charging and allows imaging of nonconducting sampl
es by scanning electron microscopy (SEM) as well as X-ray microanalysi
s. Specifically, this procedure makes it possible to perform EPMA of s
amples with xerogel matrices, which were used for molecular laser micr
oprobe mass spectrometry analysis, and consequently to provide complex
microprobe examination of samples.