Recent magnetoluminescence results obtained for homoepitaxial GaN layers ar
e presented. The neutral impurity-bound excitons and donor-acceptor pair em
ission lines have been studied in magnetic fields up to 27 T. Low-temperatu
re luminescence spectra have been measured with the magnetic field parallel
and perpendicular to the hexagonal c-axis of the GaN layers. Experimental
results allowed us to evaluate diamagnetic shifts, effective g-factors of e
lectrons and holes involved in neutral donor and neutral acceptor complexes
as well as the electron-hole exchange constant for close donor-acceptor pa
irs. Both the fine structure of the neutral acceptor-bound exciton emission
and the specific properties of donor-acceptor pair spectra observed in mag
netoluminescence experiments are tentatively attributed to the internal str
ucture of the acceptor state.