A quantitative model for ion diffusion in compacted bentonite

Compacted bentonite is a candidate backfill material for the disposal of ra dioactive waste. A correct understanding of the processes affecting diffusi on in compacted bentonite is needed to predict radionuclide migration. Using distribution coefficients (K-d) obtained in batch experiments and geo metric factors relevant for compacted bentonite, it is not possible to pred ict or explain the apparent diffusivities (D-a) typically observed. Here, a n approach is presented that integrates mechanistic sorption and diffusion models in combination with thermodynamic data and bentonite characteristics in order to predict D-a for cesium. Key features of this approach are (i) to calculate the correct K-d value at high dry densities of the bentonite, and (ii) to calculate the correct constrictivity based on an electric doubl e layer model. The integrated sorption-diffusion model present in this paper assigns excha ngeable, immobile ions to the Stem layer, whereas ions located in the diffu se layer are considered mobile. Constrictivity is interpreted as the ratio of the average concentration of an ion in the diffuse layer to its concentr ation in the bulk solution. We show that in this way, the diffusion of Ca i n Kunigel-V1 as well as Kunipia-F bentonite can be modeled successfully for a wide range of dry densities. Stern plane potentials calculated for these conditions also agree with measured zeta-potentials.