This paper reports the results obtained by studying stability characteristi
cs and ion-exchange properties of solvent-impregnated resins (SIR) obtained
by immobilization of different extractants such as, di-2-ethylhexylphospho
ric acid (DEHPA), di-2-ethylhexyldithiophosphoric acid (DEHDTPA), and di-3-
propylphenyldithiophosphoric acid (DPPDTPA) in granulated PS-DVB copolymer
Amberlite XAD-2. It has been shown that different techniques such as, conve
ntional conditioning (based on carrying out several sequential ion-exchange
cycles), 'wet drying' (boiling of SIR sample in water), and post-impregnat
ion encapsulation (coating of SIR beads with polysulfone layer) can be used
to stabilize the capacity of freshly prepared SIR samples. The stabilizing
efficiency of the last technique substantially exceeds that of two others.
The equilibrium separation factors, alpha, determined for conventionally c
onditioned SIR samples towards Zn2+ and Cd2+ mixture has been found to equa
l alpha(Zn)(Cd) = 1.6 (for DEHPA-SIR), 96.9 (DEHDTPA-SIR), and 57.6 (DPPDTP
A-SIR). The 'wet drying' procedure does not affect the selectivity of DEHPA
-SIR while that of DEHDTPA- and DPPDTPA-SIR samples substantially changes a
fter the heat treatment in water. (C) 1998 Elsevier Science B.V. AU rights
reserved.