R. Welter et al., MgTGe (T Mn, Fe) compounds of the CeFeSi-type. Magnetic structure of MgMnGe from neutron diffraction study, SOL ST COMM, 108(12), 1998, pp. 933-938
The CeFeSi-type compounds MgMnGe and MgFeGe have been prepared by reaction
of the elements at 1000 K. The magnetic properties of the MgMnGe compound h
ave been investigated by neutron diffraction. MgMnGe orders antiferromagnet
ically above room temperature. Its magnetic structure is characterized by a
staking of antiferromagnetic (0 0 1) Mn planes with the moments (approxima
te to 3.3 mu(B) at 2 K) lying in this plane. The magnetic behavior of the M
n sublattice is compared to those observed in the isotypic RMnGe and in the
closely related RMn2Ge2 and RMnSi2 (R = Ca, Sr, Ba, La and lanthanide) com
pounds. The magnetic arrangement observed in MgMnGe is connected with modif
ications in the chemical bond in this compound. (C) 1998 Elsevier Science L
td. All rights reserved.