The atomic physics relevant to the interpretation of solar spectra produced
by plasmas at temperatures greater than or similar to 10(5) K are discusse
d. Methods for determining relative abundance ratios are presented and exam
ples provided from the Coronal Diagnostic Spectrometer on board SOHO. In pa
rticular, the Fe/Si ratio in the corona is found to be close to photospheri
c; the Mg/Ne ratio in the transition region is found to vary by an order of
magnitude in different solar features. The Mg/Ne ratios in supergranule ce
ll centres and the network are separated for the first time, although no si
gnificant differences are found.