Triple-decker Complexes. 14. [1] A model for refinement of the end-for-enddisordered cationic triple-decker complex [Cp*Ru(mu-eta(5):eta(5)-C4Me4P)FeCp*]
Ge. Herberich et al., Triple-decker Complexes. 14. [1] A model for refinement of the end-for-enddisordered cationic triple-decker complex [Cp*Ru(mu-eta(5):eta(5)-C4Me4P)FeCp*], STRUCT CHEM, 9(5), 1998, pp. 359-363
The solid-state structure of the triple-decker salt [Cp*Fe(mu-eta(5):eta(5)
-C4Me4P)RUCp*]. CF3SO3 shows orientational disorder for the pseudosymmetric
cations. A chemically related compound was used to define a restrained str
ucture model. Comparison of different refinement strategies proves that thi
s restrained model is superior to an unrestrained treatment.