Zeolites are one of the most important materials currently used in the petr
oleum industry for a wide variety of catalytic transformations. However, th
ey are increasingly being considered for other applications such as for des
igning quantum-confined materials in their spaces. With such applications i
n mind, precise characterisation of zeolites and related porous materials h
as never been more necessary. Here we show how electron diffraction coupled
with high-resolution imaging can reveal the detailed fine structure in bot
h the bulk and at the surface of these materials. A variety of case studies
are considered which include ETS-IO, FAU, LTL and FSM-16. (C) 1998 Elsevie
r Science Limited. All rights reserved.