Surface X-ray diffraction has been used to determine the two-dimensional st
ructures of Bi adsorbed on Cu(100) at coverages of 0.56 and 0.60 monolayers
. At the lower coverage, a c(9 root 2 x root 2)R45 domain wall structure is
formed consisting of a uniaxial dislocation array with a single row of Bi
atoms inserted per unit cell. The p(10 x 10) structure at 0.6-monolayer cov
erage is a two-dimensional array of similar dislocations. This system prese
nts a unique opportunity to observe the structure of the vertex formed when
two dislocations cross and interact with each other. The mechanism of the
interaction is revealed by analyzing the individual displacements of the at
oms from their ideal lattice sites in both structures. (C) 1998 Elsevier Sc
ience B.V. All rights reserved.