Reaction of Cp2Ti(Me3SiC equivalent to CSiMe3) with O-trimethylsilyl-benzaldoxime under formation of a nitrile and a titana-diazacyclopentene complex

Authors
Tillack, A Arndt, P Spannenberg, A Kempe, R Zippel, T Rosenthal, U
Citation
A. Tillack et al., Reaction of Cp2Ti(Me3SiC equivalent to CSiMe3) with O-trimethylsilyl-benzaldoxime under formation of a nitrile and a titana-diazacyclopentene complex, Z ANORG A C, 624(12), 1998, pp. 2038-2042
Citations number
29
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
624
Issue
12
Year of publication
1998
Pages
2038 - 2042
Database
ISI
SICI code
0044-2313(199812)624:12<2038:ROCETC>2.0.ZU;2-8
Abstract
Cp2Ti(Me3SiC=CSiMe3) (1) reacts with O-trimethylsilyl-benzaldoxime (4) to t he titanocene-(eta(2)-benzonitrile) complex 5 and 2,5-diaza-1-titana-3-cycl opentene 7. The structure of 7 was obtained by X-ray crystal structure anal ysis (7. orthorhombic, space group P2(1)2(1)2(1), Z=4, a= 7.955(2), b=12.63 0(3), c=19.426(4) Angstrom).