V. Bonny et al., PHASE-TRANSITIONS IN DISORDERED LEAD IRON NIOBATE - X-RAY AND SYNCHROTRON-RADIATION DIFFRACTION EXPERIMENTS, Solid state communications, 102(5), 1997, pp. 347-352
Diffraction above room temperature, on powders and crystals of Pb(Fe0.
5Nb0.5)O-3, using X-rays and synchrotron radiation, led to a novel and
consistent picture of the symmetry of the phases in this disordered p
erovskite. The compound is a monoclinic ferroelectric at 293 K, underg
oes a structural transition to another ferroelectric, tetragonal state
at about 355 K and finally transforms into a cubic form at approximat
ely 376 K. (C) 1997 Elsevier Science Ltd.