Nuclear magnetism and the trivalent europium ion

Authors
Citation
B. Bleaney, Nuclear magnetism and the trivalent europium ion, APPL MAGN R, 15(2), 1998, pp. 169-172
Citations number
7
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
APPLIED MAGNETIC RESONANCE
ISSN journal
09379347 → ACNP
Volume
15
Issue
2
Year of publication
1998
Pages
169 - 172
Database
ISI
SICI code
0937-9347(1998)15:2<169:NMATTE>2.0.ZU;2-G
Abstract
Enhanced nuclear moments occur in atoms, molecules and all the transition g roups of the periodic table. They are unusually large for lanthanide ions, with electrons of the 4f group, but the mechanism responsible for enhanceme nt for other ions produces "anti-shielding" effects for the trivalent europ ium ion. These greatly reduce the effective nuclear magnetic moments in the ground state J= 0. Here it is suggested that dynamic nuclear polarization can be used to increase the effective nuclear moments, and off-set the anti -shielding. The substance is europium vanadate, "doped" with a small percen tage of samarium ions.