In spite of its technological importance, the basic mechanisms of laser nit
riding of metals and alloys are hardly understood. The nitrogen depth profi
les achieved by laser nitriding of pure iron were measured with high accura
cy by resonant nuclear reaction analysis and described by two superimposed
diffusion profiles. Using simple estimates, together with the results of ma
rker experiments and laser treatments in N-15-isotopically enriched atmosph
eres, the development of these profiles with the number of pulses can be si
mulated in excellent agreement with the experimental results. (C) 1999 Amer
ican Institute of Physics. [S0003-6951(99)04201-1].