We have developed in detail the theory of X-ray line and continuum producti
on due to atomic interactions of accelerated ions, incorporating in our cal
culations information from a broad range of laboratory measurements. We app
lied our calculations to the Orion region from which nuclear gamma-ray line
observations with the COMPTEL instrument on the Compton Gamma Ray Observat
ory (CGRO) were reported. The accelerated particles which produce this gamm
a-ray emission via nuclear reactions also produce X-ray lines via atomic in
teractions. We predict strong, relatively broad line emission in the range
from 0.5 to 1 keV, mainly due to de-excitations in fast O ions. Current ROS
AT observations of Orion do not provide unambiguous signatures for X-ray pr
oduction by accelerated ions. However, if future X-ray observations with hi
gh spectral resolution would confirm the predicted X-rays, the combined ana
lysis of the X-ray and gamma-ray data will set important constraints on the
origin of the accelerated particles and their interaction model.