New R-matrix calculations of electron impact excitation rates for transitio
ns among the 2s(2)2p, 2s2p(2), and 2p(3) levels of Ca XVI are presented. Th
ese data are subsequently used, in conjunction with recent estimates for pr
oton excitation rates, to derive theoretical electron density sensitive emi
ssion-line ratios involving 2s(2)2p-2s2p(2) transitions in the similar to 1
55-225 Angstrom wavelength range. A comparison of these with observational
data for solar flares, obtained with the Naval Research Laboratory's S082A
spectrograph on board Skylab, reveals excellent agreement between theory an
d observation. In addition, the theoretical ratios compare favorably with t
hose measured from the TEXT tokamak plasma, for which the electron temperat
ure and density have been independently determined. This provides experimen
tal support for the accuracy of the atomic data, and hence line ratio calcu
lations, employed in the present analysis.