We describe radial velocity observations of a large sample of apparently si
ngle white dwarfs (WDs), obtained in a long-term effort to discover close d
ouble-degenerate (DD) pairs, which might comprise viable Type Ia supernova
(SN Ia) progenitors. We augment the WD sample with a previously observed sa
mple of apparently single subdwarf B (sdB) stars, which are believed to evo
lve directly to the WD cooling sequence after the cessation of core helium
burning. We have identified 18 new radial velocity variables, including fiv
e confirmed sdB + WD short-period pairs. Our observations are in general ag
reement with the predictions of the theory of binary star evolution. We des
cribe a numerical method to evaluate the detection efficiency of the survey
and estimate the number of binary systems not detected because of the effe
cts of varying orbital inclination, orbital phase at the epoch of the first
observation, and the actual temporal sampling of each object in the sample
. Follow-up observations are in progress to solve for the orbital parameter
s of the candidate velocity variables.